By John E. Lind Jr. (auth.), J. Braunstein, Gleb Mamantov, G. P. Smith (eds.)
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Additional info for Advances in Molten Salt Chemistry: Volume 2
1(a). The phases indicated in the MCl-XCI 4 type systems can only exist under the equilibrium pressure of the XCl 4 reactive vapor and should be investigated in a totally sealed cryoscopic apparatus. The predicted shape of the pressure-temperature curves for various selected compositions is shown in Fig. I (b). The correspondence between these two diagrams is obtained from the following considerations. For the thermodynamic treatment the system shall be divided into two subsystems: MCl-M 2XCI 6 and M 2XCI 6-XCI 4 (Fig.
Andersen, J. Chem. Phys. 54:26 (1971). 10. J. C. Rasaiah and H. L. Friedman, J. Chem. Phys. 48:2742 (1968); 50:2965 (1969). I I. F. H. , in: Moltell Salt Chemistry (M. ), pp. 1-108, Interscience Publishers, New York (1964). 12. P. Walden, Bull. A cad. Sci. (St. Petersburg) 8:405 (1914). 13. A. Kisza and J. Hawranek, Z. physik. Chem. (Leipzig) 237:210 (1968). 14. P. Walden, Z. physik. Chem. 157:389 (1931). 15. H. Bloom and V. C. Reinsborough, Aust. J. Chem. 21:1525 (1968); 22:519 (1969). 16. R. N.
For the former, in general, solubilities decrease with increasing temperature, while for the latter the solubilities increase. " In some systems both types may be present. , (1) applying concepts from fluid mechanics, calculated an expression for the work necessary to create a spherical cavity in a real fluid. This work was then taken to represent the energy for the dissolution of a gas molecule in a liquid. Solubilities of noble gases, such as helium in benzene, appeared to satisfy the predictions from the model.
Advances in Molten Salt Chemistry: Volume 2 by John E. Lind Jr. (auth.), J. Braunstein, Gleb Mamantov, G. P. Smith (eds.)